Volume 617-618
Main Index

Pages 3-766 (15 January 2001)

Rhodium(II) mediated cyclizations of diazo alkynyl ketones Pages 3-16 Albert Padwa

Development of olefin metathesis catalyst precursors bearing nucleophilic carbene ligands Pages 17-27 Laleh Jafarpour, Steven P. Nolan

Carbenes with ferrocenyl substituents Pages 28-38 Benno Bildstein

Bis(iodozincio)methane — preparation, structure, and reaction Pages 39-46 Seijiro Matsubara, Koichiro Oshima, Kiitiro Utimoto

Recent progress in asymmetric intermolecular C---H activation by rhodium carbenoid intermediates Pages 47-55 Huw M. L. Davies, Evan G Antoulinakis

Factors governing the equilibrium between metal---alkyl, alkylidene and alkylidyne: MCX2R, X---M=CXR and X2MCR Pages 56-64 Kenneth G. Caulton

Coordination chemistry of CNH2, the simplest aminocarbyne Pages 65-69 Armando J. L. Pombeiro, M. Fátima, C. Guedes da Silva

Synthesis of chiral triazolinylidene and imidazolinylidene transition metal complexes and first application in asymmetric catalysis Pages 70-80 Dieter Enders, Heike Gielen

Carbene complexes of titanium group metals — formation and reactivity Pages 81-97 Rüdiger Beckhaus, Cristina Santamaría

Catalyst selection for metal carbene transformations Pages 98-104 Daren J. Timmons, Michael P. Doyle

Some aspects of the Lewis base and ligand behavior of N-heterocyclic carbenes Pages 105-109 Alan H. Cowley

The use of polypyrazolylborate copper(I) complexes as catalysts in the conversion of olefins into cyclopropanes, aziridines and epoxides and alkynes into cyclopropenes Pages 110-118 M. Mar Díaz-Requejo, Pedro J. Pérez

Metal glycosylidenes: novel organometallic tools for C-glycosidation: Part 19. Organotransition metal modified sugars Pages 119-132 Karl Heinz Dötz, Christoph Jäkel, Wilm-Christian Haase

Luminescent metal complexes derived from carbene and related ligands: tuning excited-state properties with metal–carbon multiple bonds Pages 133-140 Siu-Wai Lai, Michael C. W. Chan, Yue Wang, Hiu-Wah Lam, Shie-Ming Peng, Chi-Ming Che

Cyclopropenation of organometallic vinylidene complexes Pages 141-147 Ying-Chih Lin

Early transition metal carbenoid reagents in epimetallation and metallative dimerization of unsaturated organic substrates Pages 148-157 John J. Eisch

Early transition metal and lanthanide bis(iminophosphorano)methandiide complexes; ‘pincer’ and bridging bis(phosphorus) metal carbenes Pages 158-169 Ronald G. Cavell, Ruppa P. Kamalesh Babu, Kasani Aparna

Carbene complexes derived from lithiated heterocycles, mainly azoles, by transmetallation Pages 170-181 Helgard G. Raubenheimer, Stephanie Cronje

The preparation of imidazolidinone and oxazolidinone chelated carbene complexes Pages 182-208 Timothy S. Powers, William D. Wulff, John Quinn, Yan Shi, Weiqin Jiang, Richard Hsung, Mark Parisi, Annette Rahm, Xiao Wu Jiang, Glenn P. A. Yap, Arnold L. Rheingold

Chemistry of thermally stable bis(amino)silylenes Pages 209-223 Barbara Gehrhus, Michael F. Lappert

Two possible reaction pathways for the formation of a ruthenium carbene complex by addition of acetylene to [RuH2Cl2(PH3)2]: a quantum chemical study Pages 225-232 Nicole Dölker, Gernot Frenking

Activation of 2-propyn-1-ols by the rhenium(I) fragment [{MeC(CH2PPh2)3}Re(CO)2]+. Synthesis and characterization of cationic Re(I) complexes containing unsaturated η1-carbon ligands Pages 233-241 Claudio Bianchini*, Nicoletta Mantovani, Lorenza Marvelli, Maurizio Peruzzini*, Roberto Rossi*, Antonio Romerosa

Synthesis and reactivity of subvalent compounds: Part 11. Oxidation, hydrogenation and hydrolysis of stable diamino carbenes Pages 242-253 Michael K. Denk, José M. Rodezno, Shilpi Gupta, Alan J. Lough

Photochemical C–H bond activation of diruthenium bridging alkylidene complexes: Interligand H-exchange on Cp2Ru2(μ-CH2)(μ-CHR)(CO)2 (R=H, Me) Pages 254-260 Munetaka Akita, Hideki Musashi, Sadahiro Nakanishi, Yoshihiko Moro-oka

Intramolecular carbon–carbon coupling reactions of a κ2(P,P)-bis(diphenylphosphino)methanide ligand with unsaturated carbene moieties in indenyl–ruthenium(II) complexes Pages 261-268 Victorio Cadierno, M. Pilar Gamasa, José Gimeno, Blanca M. Martín-Vaca

A matrix isolation and flash photolysis study of the cyclization reactions of chromium amino carbenes Pages 269-279 K. O. Doyle, M. L. Gallagher, M. T. Pryce, A. D. Rooney

Synthesis and crystal structures of carbene complexes with conjugated thiophene units Pages 280-287 Marilé Landman, Helmar Görls, Simon Lotz

Facile synthesis of a ruthenium carbene complex with a cis-chelating diphosphinoethane ligand Pages 288-291 Martin A. O. Volland, Bernd F. Straub, Irene Gruber, Frank Rominger, Peter Hofmann

Reactions of di-μ-carbonyl-cis-μ-(1-5-η:1′-5′-η-dicyclopentadienyl-dimethylsilane)bis(carbonyliron) with aryllithium reagents. Crystal structures of [Fe2(μ-CO){μ-C(OC2H5)C6H5}(CO)2{(η5-C5H4)2Si(CH3)2}] and [Fe2(μ-CO){μ-C(OC2H5)C6H4OCH3-p}(CO)2{(η5-C5H4)2Si(CH3)2}] Pages 292-300 Ruitao Wang, Jie Sun, Jiabi Chen

Synthesis and reactivity of neutral vinylidene and σ-alkynyl complexes containing the hemilabile ligand Ph2PCH2CH2OMe: Part 16. Ruthenium tris(pyrazolyl)borate complexes Pages 301-310 Sonja Pavlik, Christian Gemel, Christian Slugovc, Kurt Mereiter, Roland Schmid, Karl Kirchner

Phosphinidene reactivity toward unsaturated phosphorus heterocycles Pages 311-317 Mark J. M. Vlaar, Frans J. J. de Kanter, Marius Schakel, Martin Lutz, Anthony L. Spek, Koop Lammertsma

Preparation and structural features of new dialkylamino-substituted cyclopropenylidenepentacarbonylchromium complexes Pages 318-321 Armin de Meijere, Stephan Müller, Thomas Labahn

Rearrangement of carbiminium carbonylmetalates by mutual exchange of alkoxy- and amino functionalities (M=W, Cr): Crystal structure analyses Pages 322-328 Rudolf Aumann, Klaus Roths, Roland Fröhlich

Reaction of iron aminocarbene complexes with electronically deficient alkenes Pages 329-333 Ivan Rotrekl, Libor Vyklický, Dalimil Dvorák

Tethering strategies in alkynylamino carbene complexes Pages 334-338 Josep M. Moretó, Susagna Ricart

(Diazomethyl)silyl-functionalized Fischer-type carbene complexes Pages 339-345 Gerhard Maas, Dieter Mayer

Chelated η2-alkene- and η3-allyl-carbene complexes of late transition metals: structure–reactivity relations and preparative use: Part 10. The chemistry of metallacyclic alkenylcarbene complexes Pages 346-359 Rainer Schobert

Ruthenium–porphyrin-catalyzed carbenoid addition to allylic compounds: application to [2,3]-sigmatropic rearrangements of ylides Pages 360-363 Gérard Simonneaux, Erwan Galardon, Christine Paul-Roth, Mihaela Gulea, Serge Masson

Helical mono and dinuclear mercury(II) N-heterocyclic carbene complexes Pages 364-375 Kwang-Ming Lee, Jack C. C. Chen, Ivan J. B. Lin

Transition metal (‘Fischer-type’) carbene complexes as protein labelling reagents Pages 376-382 Michèle Salmain, Emanuela Licandro, Clara Baldoli, Stefano Maiorana, Hoa Tran-Huy, Gérard Jaouen

Complexes with phosphorus analogues of imidazoyl carbenes: unprecedented formation of phosphenium complexes by coordination induced P---Cl bond heterolysis Pages 383-394 Dietrich Gudat, Asadollah Haghverdi, Martin Nieger

1,1′-(Pyridine-2,6-diyl)bis(3-benzyl-2,3-dihydro-1H-imidazol-2-ylidene), a new multidentate N-heterocyclic biscarbene and its silver(I) complex derivative Pages 395-398 Agustín Caballero, Enrique Díez-Barra*, Félix A. Jalón, Sonia Merino, Juan Tejeda*

Fischer-type alkyl(hydrazino)carbene complexes: new synthetic potential in comparison with aminocarbene complexes Pages 399-411 Emanuela Licandro, Stefano Maiorana, Dario Perdicchia, Clara Baldoli, Claudia Graiff, Antonio Tiripicchio

New carbene and vinylidene chelate complexes of cyclopentadienylcobalt bearing a phosphorus tether Pages 412-422 Jan Foerstner, Alf Kakoschke, Richard Goddard, Jörg Rust, Rudolf Wartchow, Holger Butenschön

Stereochemically defined metal carbene complexes as chemical probes for studies of the ring formation of 2H-azaphosphirene complexes Pages 423-434 Rainer Streubel, Siegfried Priemer, Jörg Jeske, Peter G. Jones

Schrock type transition metal complex formation of push–pull substituted phosphanyl-carbenes, a quantum chemical investigation by density-functional methods Pages 435-443 Wolfgang W. Schoeller, Alexander J. B. Rozhenko, Alexander Alijah

Discovery of the tungsten carbonyl-catalyzed endo-selective alkynyl alcohol cycloisomerization reaction: applications to stereoselective syntheses of -olivose, -olivose disaccharide substructures of landomycin and mithramycin Pages 444-452 Frank E. McDonald, K. Subba Reddy

Conversion of a stannyl---phosphenium complex into a stannylene---phosphine complex of Mo and W: double bond migration from MP to MSn Pages 453-463 Hiroshi Nakazawa*, Mitsuru Kishishita, Takeshi Ishiyama, Tsutomu Mizuta, Katsuhiko Miyoshi*

Aminolysis of 3-alkoxysubstituted cyclobutenylidene complexes. A novel convenient route to chiral 3-aminosubstituted cyclobutenylidene complexes Pages 464-472 Christoph C. Karl, Stefan Joneleit, Kerstin Weißenbach, Helmut Fischer

Electrophilic C(2)-functionalization of nitronyl nitroxides: a reference to N-heterocyclic carbenes Pages 473-482 Robert Weiss, Norbert Kraut, Frank Hampel

Mechanism of formation of the metallacyclic iron carbenes (CO)3)NR2] formed by thermal evolution of bis carbamoyl complexes, characterization of η2-carbamoyl intermediates Pages 483-494 Nathalie Le Gall, Denis Luart, Jean-Yves Salaün, Hervé des Abbayes, Loïc Toupet

Reactions of molybdenum and tungsten alkyl and aryl complexes that contain a triamidoamine ligand with carbon monoxide Pages 495-501 Richard R. Schrock, Celine Rosenberger, Scott W. Seidel, Keng-Yu Shih, William M. Davis, Aaron L. Odom

Synthesis and molecular structure of four-coordinate neutral and cationic diphenylcarbenerhodium(I) complexes Pages 502-510 Elke Bleuel, Birgit Weberndörfer, Helmut Werner

Neutral carbene and vinylidene cyclopentadienyl ruthenium complexes with PPh2(2-MeC6H4) Pages 511-519 Walter Baratta*, Alessandro Del Zotto, Eberhardt Herdtweck, Sara Vuano, Pierluigi Rigo*

X-ray structure and electrophilic reactivity of a cationic, chiral tungsten(II) methylene complex Pages 520-529 Aase S. Jepsen, Neil J. Vogeley, Peter S. White, Joseph L. Templeton

Homoleptic carbene complexes: Part VIII. Hexacarbene complexes Pages 530-545 Robert Fränkel, Ulrich Kernbach, Maria Bakola-Christianopoulou, Ulrike Plaia, Max Suter, Werner Ponikwar, Heinrich Nöth, Claude Moinet, Wolf Peter Fehlhammer

Palladium(II) complexes containing mono-, bi- and tridentate carbene ligands. Synthesis, characterisation and application as catalysts in C---C coupling reactions Pages 546-560 Alison M. Magill, David S. McGuinness, Kingsley J. Cavell, George J. P. Britovsek, Vernon C. Gibson, Andrew J. P. White, David J. Williams, Allan H. White, Brian W. Skelton

Methylidene and hydrazone complexes of the cluster family: Cp′3M3(CO)2(CH2) (M=Co, Rh, Ir) Pages 561-570 Frank Holger Försterling, Craig E. Barnes

Tungsten(0) alkylidene complexes stabilized as pyridinium ylides: new aspects of their synthesis and reactivity Pages 571-587 Henri Rudler, Thomas Durand-Réville

Metallocenes of the alkaline earth metals and their carbene complexes Pages 588-600 Herbert Schumann, Jochen Gottfriedsen, Mario Glanz, Sebastian Dechert, Jörg Demtschuk

Synthesis and characterization of planar-chiral cyclopentadienylruthenium–vinylidene complexes Pages 601-615 Yoshiki Ajioka, Yuji Matsushima, Kiyotaka Onitsuka, Hiroshi Yamazaki, Shigetoshi Takahashi

Synthesis, structure and catalytic application of palladium(II) complexes bearing N-heterocyclic carbenes and phosphines Pages 616-628 Wolfgang A. Herrmann, Volker P. W. Böhm, Christian W. K. Gstöttmayr, Manja Grosche, Claus-Peter Reisinger, Thomas Weskamp

A zwitterionic carbene–stannylene adduct via cleavage of a dibenzotetraazafulvalene by a stannylene Pages 629-634 F. Ekkehardt Hahn, Lars Wittenbecher, Michaela Kühn, Thomas Lügger, Roland Fröhlich

An improved synthesis of bis(1,3-di-N-tert-butylimidazol-2-ylidene)palladium(0) and its use in C–C and C–N coupling reactions Pages 635-639 Stephen Caddick, F. Geoffrey N. Cloke*, Guy K. B. Clentsmith, Peter B. Hitchcock, Darren McKerrecher, Lisa R. Titcomb, Meredith R. V. Williams

2-Azaallenylidene complexes: syntheses and structures of chromium and tungsten complexes with a (cyclopropenylidene)-2-azaethenylidene ligand Pages 640-646 Matthias Tamm, Thomas Bannenberg, Alexander Grzegorzewski, Roland Fröhlich

Evidence for multiple bonding in four-coordinate, cationic, platinum---thiosilylenes via AIM and CDA; effects of phosphine choice Pages 647-655 Frederick P. ArnoldJr.

Aminomethylene complexes of molybdenum(IV) and tungsten(IV) bearing 1,2-dithiolato ligands Pages 656-670 Alexander C. Filippou, Peter Portius, Christel Jankowski

Some reactions of the platinum(II) carbene complex cis-dichloro(dimethylaminomethylene)(triphenylphosphine)platinum(II) and the X-ray crystal and molecular structures of the products trans-(CH2,P)-chloro(chloromethyl)(dimethylaminomethylene)(triphenylphosphine)platinum(II) and [1,2-bis(diphenylphosphino)ethane](dimethylaminomethylene)(triphenylphosphine)platinum(II) bis(hexafluorophosphate) Pages 671-680 George Ferguson, Yiwei Li, Alan J. McAlees, Robert McCrindle, Erle Zang

Synthesis and reactivity of μ-bis(carbene)dimanganese complexes. X-ray structures of {Cp′(CO)2Mn}2{μ-=C(OEt)CH2CH2(EtO)C=}, (E)-{Cp′(CO)2Mn}2{μ-=C(OEt)CH=CH(EtO)C=} and {Cp′(CO)2Mn}2{μ-=H=} Pages 681-695 Alain Rabier, Noël Lugan, René Mathieu

Terminal chloroaminophosphido and aminophosphinidene complexes of molybdenum Pages 696-701 Brian T. Sterenberg, Arthur J. Carty

Reinvestigation of the chemoselective cyclopropanation of allylic alcohols, allylic ethers and alkenes: a comparison between various reagents and protocols Pages 702-708 André B. Charette, André Beauchemin

Solution and solid state conformation of Fischer carbene complexes vis-à-vis conformation of aryl carboxamides: complexation of the aromatic ring by tricarbonylchromium makes a difference Pages 709-722 K. N. Jayaprakash, Debasis Hazra, Karl S. Hagen, Uttamkumar Samanta, Mohan M. Bhadbhade, Vedavati G. Puranik, Amitabha Sarkar

Reaction of rhenium alkynyl carbene complexes with tertiary phosphines produces dihydrophospholium rhenium complexes by a formal CH insertion process Pages 723-736 Charles P. Casey, Stefan Kraft, Douglas R. Powell, Michael Kavana

Synthesis and reactivity of subvalent compounds: Part 10. Fast deuterium labeling and the basicity of stable diamino carbenes (imidazole-2-ylidenes) Pages 737-740 Michael K. Denk, José M. Rodezno

Reactions of silyl-substituted Fischer-type carbene complexes with silanes Pages 741-743 Nobuharu Iwasawa, Masatoshi Saitou, Hiroyuki Kusama

Formation of carbenoid intermediates in the reaction of ditertiobutyl ketone with low-valent titanium reagents Pages 744-747 Claude Villiers, Alain Vandais, Michel Ephritikhine

Synthesis and X-ray crystal structure analysis of a phosphorus analogue of (1,2,3-η)-trans-butadienyl complexes Pages 748-750 Ngoc Hoa Tran Huy, Louis Ricard, François Mathey

The origin of diastereoselectivity in cyclopropanation reactions of the iron carbene complex [(η5-C5H5)(CO)2Fe=CH[(η6-o-CH3OC6H4)Cr(CO)3]]+ Pages 751-754 Qinwei Wang, M. Mahmun Hossain

Index Pages 755-756 Unknown

Index Pages 757-766 Unknown